Achievement of visible-light-driven Z-scheme overall water splitting using barium-modified Ta3N5 as a H2-evolving photocatalyst† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c6sc02750d Click here for additional data file.

نویسندگان

  • Yu Qi
  • Shanshan Chen
  • Mingrun Li
  • Qian Ding
  • Zheng Li
  • Junyan Cui
  • Beibei Dong
  • Fuxiang Zhang
  • Can Li
چکیده

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Achievement of visible-light-driven Z-scheme overall water splitting using barium-modified Ta3N5 as a H2-evolving photocatalyst.

Ta3N5 is one of the most promising photocatalyst candidates for solar water splitting, but it still remains challenging to achieve overall water splitting via Ta3N5-based photocatalysts regardless of whether it uses a one step or two step method. Here we will address the relatively poor photocatalytic proton reduction of Ta3N5 with an effort for the promotion of charge separation via barium mod...

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Hybrid photocathode consisting of a CuGaO2 p-type semiconductor and a Ru(ii)–Re(i) supramolecular photocatalyst: non-biased visible-light-driven CO2 reduction with water oxidation† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c7sc00940b Click here for additional data file.

A CuGaO2 p-type semiconductor electrode was successfully employed for constructing a new hybrid photocathode with a Ru(II)–Re(I) supramolecular photocatalyst (RuRe/CuGaO2). The RuRe/CuGaO2 photocathode displayed photoelectrochemical activity for the conversion of CO2 to CO in an aqueous electrolyte solution with a positive onset potential of +0.3 V vs. Ag/AgCl, which is 0.4 V more positive in c...

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عنوان ژورنال:

دوره 8  شماره 

صفحات  -

تاریخ انتشار 2017